Crystal structures and disorder in two heterobimetallic polysulfido complexes
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Two-dimensional cyanide-bridged heterobimetallic complexes based on CpCoðCNÞ3 : Syntheses, structures and magnetic properties
Using the half-sandwich tricyanometalate, KCpCo(CN)3 (1, Cp = cyclopentadienyl), as the building block, two new cyano-bridged heterobimetallic complexes, [{CpCo(CN)3}2M(H2O)2] Æ 2H2O (M = Fe , 2; Co, 3), have been synthesized and structurally characterized. Complexes 2 and 3 are isostructural. In each complex, [CpCo(CN)3] acts as a bis-monodentate bridging ligand toward the central [M(H2O)2] 2+...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 1996
ISSN: 0108-7673
DOI: 10.1107/s0108767396087405